New Glycosides of Lignin

نویسندگان

  • D. Joniak
  • M. Polakova
چکیده

New biodegradable surface active agents were prepared by glycosidation of prehydrolysis lignin with the D-glucose using anhydrous ferric chloride as the catalyst which afforded polymeric alkyl, benzyl and aryl glucofuranoside derivatives of lignin. Moreover, a series of novel lignin-based surface active agents was obtained by subsequent Oxidation of the primary alcohol groups of u-glucose into carboxyl groups by 2,2,6,6,-tetramethyl1-piperidine oxoammonium ions with sodium hypochlorite and sodium bromide in an aqueous alkaline Solution at pH 11.

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تاریخ انتشار 2002